Document Type

Journal Article

Department/Unit

School of Chinese Medicine

Title

Iridium-catalyzed asymmetric hydroalkynylation reactions of oxabenzonorbornadienes

Language

English

Abstract

Oxabenzonorbornadienes were found to be suitable substrates for asymmetric hydroalkynylation reactions. Catalyzed by the complex of [Ir(COD)Cl]2 and (R)-SYNPHOS, oxabenzonorbornadienes and terminal alkynes could react smoothly to give the alkynylated products in moderate to good yields (up to 93% yield) and enantioselectivities (up to 85% ee). © The Royal Society of Chemistry 2013.

Publication Date

2013

Source Publication Title

Organic and Biomolecular Chemistry

Volume

11

Issue

5

Start Page

814

End Page

820

Publisher

Royal Society of Chemistry

DOI

10.1039/c2ob26775f

Link to Publisher's Edition

http://dx.doi.org/10.1039/c2ob26775f

ISSN (print)

14770520

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