http://dx.doi.org/10.1055/s-0029-1216639">
 

Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Sulfonyl Hydrazine as New Functionality in Organocatalysis: Camphorsulfonyl Hydrazine Catalyzed Enantioselective Aza-Michael Addition

Language

English

Abstract

Sulfonyl hydrazine is a new functionality for the Lewis base organocatalysis. Nα-substituted camphorsulfonyl hydrazines (CaSH) are effective organocatalysts for the asymmetric aza-Michael addition to α,β-unsaturated aldehydes with enantioselectivity of up to 90%. © Georg Thieme Verlag Stuttgart.

Keywords

α, β-unsaturated aldehyde, Aza-Michael addition, Camphorsulfonyl hydrazine, Organocatalysis, Sulfonyl hydrazine

Publication Date

2009

Source Publication Title

Synthesis-Stuttgart

Issue

9

Start Page

1573

End Page

1577

Publisher

Thieme Publishing

ISSN (print)

00397881

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