Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Efficient electrophosphorescence from a platinum metallopolyyne featuring a 2,7-carbazole chromophore

Language

English

Abstract

The synthesis, thermal and emission properties of an electrophosphorescent platinum (II) metallopolyyne polymer consisting of 9-butylcarbazole-2,7-diyl spacer P1 are described. The optical and electronic properties of P1 are compared to their molecular diplatinum (II) and digold (I) model complexes. The photophysical properties of P1 are somehow analogous to its 2,7-fluorene-linked congener but differs significantly from that for the 3,6-carbazole derivative. Its optical band gap is notably reduced as compared to that for the 3,6-carbazole analog. Multi-layer polymer light-emitting diodes (PLEDs) were fabricated with P1 as the emitting layer which gave a strong green-yellow electrophosphorescence. The best PLED can reach the maximum current efficiency of 4.7 cd. A-1 at 5 wt.-% doping level, corresponding to an external quantum efficiency of 1.5%. This represents the first literature example of efficient PLEDs exhibiting pure triplet emission under electrical excitation for metallopolyynes without the concomitant singlet emission. For safety concern, this was also tested for possible cytotoxicity and it does not show significant cytotoxic activity on liver and breast derived human cells at reasonable doses, rendering this functional material safe to use in practical devices. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords

Alkyne, Metallopolymer, Phosphorescence, Photophysics, Polymer light-emitting device, Transition metal

Publication Date

2009

Source Publication Title

Macromolecular Chemistry and Physics

Volume

210

Issue

21

Start Page

1786

End Page

1798

Publisher

Wiley-VCH Verlag

DOI

10.1002/macp.200900351

Link to Publisher's Edition

http://dx.doi.org/10.1002/macp.200900351

ISSN (print)

10221352

ISSN (electronic)

15213935

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