Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Facile separation catalyst system: direct diastereoselective synthesis of (E)-α,β-unsaturated ketones catalyzed by an air-stable Lewis acidic/basic bifunctional organobismuth complex in ionic liquids

Language

English

Abstract

The catalyst system that comprises an air-stable bifunctional Lewis acidic/basic organobismuth complex and [Bmim]BF4 is highly efficient in the cross-condensation of aldehydes with ketones. Through switching the reaction from homogeneous to heterogeneous, the system shows facile separation ability and facile reusability. © 2010 The Royal Society of Chemistry.

Publication Date

2010

Source Publication Title

Green Chemistry

Volume

12

Issue

10

Start Page

1767

End Page

1771

Publisher

Royal Society of Chemistry

DOI

10.1039/C004940A

Link to Publisher's Edition

http://dx.doi.org/10.1039/C004940A

ISSN (print)

14639262

ISSN (electronic)

14639270

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