Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Highly efficient and selective synthesis of (E)-α,β-unsaturated ketones by crossed condensation of ketones and aldehydes catalyzed by an air-stable cationic organobismuth perfluorooctanesulfonate

Language

English

Abstract

An air-stable cationic organobismuth perfluorooctanesulfonate possessing both acidic and basic characters was synthesized, and showed high catalytic activity, diastereoselectivity, stability, and reusability in the one-pot synthesis of (E)-α,β-unsaturated ketones through highly selective crossed condensation of ketones and aldehydes in water. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

(e)-α, β-unsaturated ketones, Crossed condensation, Diastereoselectivity, Organobismuth compounds, Perfluorooctanesulfonates

Publication Date

2010

Source Publication Title

Advanced Synthesis and Catalysis

Volume

352

Issue

1

Start Page

153

End Page

162

Publisher

Wiley-VCH Verlag

DOI

10.1002/adsc.200900679

Link to Publisher's Edition

http://dx.doi.org/10.1002/adsc.200900679

ISSN (print)

16154150

ISSN (electronic)

16154169

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