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Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Practical synthetic approach to chiral sulfonimides (CSIs) – chiral Brønsted acids for organocatalysis

Language

English

Abstract

A general approach to the synthesis of optically pure 3,3'diaryl chiral sulfonimides (CSIs) from racemic BINOL has been developed. ortho-Lithiation is directed by the sulfonyl groups, and the resulting dihalides serve as the common precursors for the aryl-substituted CSIs. © 2010 Wiley-VCH Verlag GmbH &, Co. KGaA, Weinheim.

Keywords

Bransted acids, Chirality, Organocatalysis, Sulfonimides

Publication Date

2010

Source Publication Title

European Journal of Inorganic Chemistry

Volume

2010

Issue

22

Start Page

4181

End Page

4184

Publisher

Wiley-VCH Verlag

ISSN (print)

14341948

ISSN (electronic)

10990682

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