Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Synthesis and structure of an air-stable hypervalent organobismuth (III) perfluorooctanesulfonate and its use as high-efficiency catalyst for Mannich-type reactions in water

Language

English

Abstract

An air-stable hypervalent organobismuth (III) perfluorooctanesulfonate was synthesized and characterized by spectroscopic and X-ray crystallographic techniques, and found to exhibit high catalytic efficiency towards one-pot Mannich-type reaction of ketones with aromatic aldehydes and aromatic amines in water. This catalyst also shows good recyclability and reusability. This catalytic system would provide a simple, efficient and 'green' avenue towards the synthesis of β-amino ketones. © 2009.

Keywords

Crystal structure, Mannich, Organobismuth, Perfluorooctanesulfonate, Three-component reaction

Publication Date

2009

Source Publication Title

Journal of Organometallic Chemistry

Volume

694

Issue

22

Start Page

3559

End Page

3564

Publisher

Elsevier

DOI

10.1016/j.jorganchem.2009.07.018

ISSN (print)

0022328X

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