Department of Chemistry
Synthesis, characterization and photophysical properties of metallopolyynes and metallodiynes of platinum(II) with dibenzothiophene derivatives
Soluble, thermally stable, and easily processable platinum(II) polyyne polymers of the form trans-[-Pt(PBu3)2C≡CRC≡C-]n (R = 2,8-disubstituted dibenzothiophene, 2,8-disubstituted and 3,7-disubstituted dibenzothiophene-S,S-dioxide units) have been prepared in good yields by CuI-catalyzed polymerization involving the dehydrohalogenating coupling of trans-[PtCl2(PBu3)2] and HC≡CRC≡CH. We report their optical absorption and photoluminescence spectra and compare the results with the monomeric model complexes trans-[Pt(Ph)(PEt3)2C≡CRC≡CPt(Ph)(PEt3)2]. The different electronic properties and linkage geometry of the central R group lead to new organometallic materials with distinct photophysical traits. The polymer with more conjugated 3,7-disubstituted dibenzothiophene-S,S-dioxide mainly displays fluorescence band, while its isomer with less conjugated 2,8-disubstituted spacer effectively enhances the intersystem crossing rate and strong phosphorescence emission can be detected even at room temperature. © 2012 Springer Science+Business Media New York.
Acetylide, Dibenzothiophene, Photoluminescence, Platinum, Sulfone
Source Publication Title
Journal of Inorganic and Organometallic Polymers and Materials
Link to Publisher's Edition
Ho, Cheuk-Lam, Suk-Yue Poon, Pik-Kwan Lo, Man-Shing Wong, and Wai-Yeung Wong. "Synthesis, characterization and photophysical properties of metallopolyynes and metallodiynes of platinum(II) with dibenzothiophene derivatives." Journal of Inorganic and Organometallic Polymers and Materials 23.1 (2013): 206-215.