http://dx.doi.org/10.1021/ic9020178">
 

Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Trans-[OsIII(salen)(CN)2]−: A new paramagnetic building block for the construction of molecule-based magnetic materials

Language

English

Abstract

A novel dicyanoosmium(III) complex, trans-Ph4P[Os III(salen)(CN)2]* CH2Cl2 * H2O (1; Ph4 P+ = tetraphenylphosphonium cation, salen2-=N, N′-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me3tacn)(H2O)2](ClO4) 2 (Me3tacn=1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)2]2[Cu(Me3tacn)] * CH 3OH (2) and [Os(salen)(CN)2][Cu(Me3tacn)] * ClO4 (3). © 2010 American Chemical Society.

Publication Date

2010

Source Publication Title

Inorganic Chemistry

Volume

49

Issue

4

Start Page

1607

End Page

1614

Publisher

American Chemical Society

ISSN (print)

00201669

ISSN (electronic)

1520510X

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