Department of Chemistry
8-Quinolinolato complexes of ruthenium(II) and (III)
Reduction of RuQ3 (1a, Q = 8-quinolinolato) with Zn/Hg in the presence of various π-acceptor ligands in ethanol affords RuQ2L2 (L2 = (dimethylsulfoxide)2 (2); (4-picoline)2 (3); N,N′-dimethyl-1,4-diazabuta-1,3-diene, dab (4); cyclooctadiene, COD (5); norborna-2,5-diene, nbd (6)). Compound 6 is isolated as an equimolar mixture of cis,trans (6a) and trans,cis (6b) isomers, which can be separated by column chromatography. DFT calculations have been performed on 6a and 6b. Oxidation of 3 and 6b affords the corresponding ruthenium(III) species 7 and 8, respectively. The structures of 2, 3, 4 and 6 have been determined by X-ray crystallography. © 2008 Elsevier B.V. All rights reserved.
8-Quinolinolate, Alkene, Nitrogen ligands, Ruthenium
Source Publication Title
Inorganica Chimica Acta
Link to Publisher's Edition
Leung, Chi-Fai, Chun-Yuen Wong, Chi-Chiu Ko, Man-Chong Yuen, Wing-Tak Wong, Wai-Yeung Wong, and Tai-Chu Lau. "8-Quinolinolato complexes of ruthenium(II) and (III)." Inorganica Chimica Acta 362.4 (2009): 1149-1157.