http://dx.doi.org/10.1039/C2CC35947B">
 

Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Hydrogen shuttling: Synthesis and reactivity of a 14-electron iridium complex featuring a bis(alkyl) tethered N-heterocyclic carbene ligand

Language

English

Abstract

Solvent dependent double C-H activation in an Ir(NHC)2 system generates an agostically stabilized 14-electron complex featuring a face-capping bis(alkyl) tethered NHC ligand [NHC = N-heterocyclic carbene]. These activation processes are reversible, and the resulting ligand-derived hydrogen shuttle can be applied to the dehydrogenation of BN-containing substrates. © The Royal Society of Chemistry.

Publication Date

2012

Source Publication Title

Chemical Communications

Volume

48

Issue

98

Start Page

11999

End Page

12001

Publisher

Royal Society of Chemistry

ISSN (print)

13597345

ISSN (electronic)

1364548X

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