Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Synthesis, structure and applications of hypervalent organoantimony compounds having intramolecular E→Sb (E = N, O, S) coordinations

Language

English

Abstract

The review article covers the hypervalent organoantimony compounds that are with intramolecular N, O, S→Sb coordinations synthesized in the past 20 years. We describe their structures and the related coordination chemistry, highlighting a number of hypervalent stibines. These compounds have shown many applications in organic synthesis. They are useful reagents for reactions such as crosscoupling and arylation with organic halides, and addition with carbonyl compounds. They can be used as Lewis acid catalysts in organic synthesis. Furthermore, they can be utilized as catalysts or reagents for CO2 chemical fixation. It is envisaged that more hypervalent organoantimony compounds of novel structure will be synthesized and find new applications in the near future. © 2012 Bentham Science Publishers.

Keywords

Catalyst, Hypervalent compounds, Intramolecular coordination, Organic synthesis, Organoantimony, Reagent, Structure

Publication Date

2012

Source Publication Title

Current Organic Chemistry

Volume

16

Issue

20

Start Page

2462

End Page

2481

Publisher

Bentham Science Publishers

DOI

10.2174/138527212803520083

Link to Publisher's Edition

http://dx.doi.org/10.2174/138527212803520083

ISSN (print)

13852728

ISSN (electronic)

18755348

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