School of Chinese Medicine
Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex
© 2014 Published by Elsevier Ltd. As an efficient catalyst, the [Ir(COD)Cl]2/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72-98%) with good enantioselectivities (80-90% ee).
ARO reaction (S)-NMDPP Amines, Oxabenzonorbornadienes
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Yu, Lu, Yongyun Zhou, Xin Xu, Sifeng Li, Jianbin Xu, Baomin Fan, Chengyuan Lin, Zhaoxiang Bian, and Albert S.C. Chan. "Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex." Tetrahedron Letters 55.46 (2014): 6315-6318.