School of Chinese Medicine
Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex
© 2014 Published by Elsevier Ltd. As an efficient catalyst, the [Ir(COD)Cl]2/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72-98%) with good enantioselectivities (80-90% ee).
ARO reaction (S)-NMDPP Amines, Oxabenzonorbornadienes
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Yu, L., Zhou, Y., Xu, X., Li, S., Xu, J., Fan, B., Lin, C., Bian, Z., & Chan, A. (2014). Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex. Tetrahedron Letters, 55 (46), 6315-6318. https://doi.org/10.1016/j.tetlet.2014.09.089