Document Type

Journal Article

Department/Unit

Department of Chemistry

Title

Novel Zn(II) coordination polymer based on 1,2-bis (4-pyridyl)hydrazine - From two-dimensional to three-dimensional network

Language

English

Abstract

Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell. © 2011 Published by NRC Research Press.

Keywords

1, 2-bis(4-pyridyl)hydrazine, Coordination polymer, Hydrogen bond, Interpenetrating polymer, Metal organic framework, Microporous

Publication Date

2012

Source Publication Title

Canadian Journal of Chemistry-Revue Canadienne De Chimie

Volume

90

Issue

1

Start Page

100

End Page

107

Publisher

Canadian Society for Chemistry

DOI

10.1139/V11-132

Link to Publisher's Edition

http://dx.doi.org/10.1139/V11-132

ISSN (print)

00084042

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