Document Type
Journal Article
Department/Unit
Department of Chemistry
Title
Novel Zn(II) coordination polymer based on 1,2-bis (4-pyridyl)hydrazine - From two-dimensional to three-dimensional network
Language
English
Abstract
Two MOFs were reported based on Zn(II) with 1,2-bis(4-pyridyl)hydrazine (L1); a two-dimensional interpenetrating MOF I of formula [Zn 2(L1) 2(L2) 2] ∞ was formed with terephthalic acid (L2) as an additional linker. A three-dimensional MOF II of formula [Zn 2(L1) 2(L3) 2] ∞, was formed with the use of a larger spacer 2,6-naphthalenedicarboxylic acid (L3). MOF II consists of large porosity with a total volume of 3746 Å 3 that occupies 34.1% of the unit cell. © 2011 Published by NRC Research Press.
Keywords
1, 2-bis(4-pyridyl)hydrazine, Coordination polymer, Hydrogen bond, Interpenetrating polymer, Metal organic framework, Microporous
Publication Date
2012
Source Publication Title
Canadian Journal of Chemistry-Revue Canadienne De Chimie
Volume
90
Issue
1
Start Page
100
End Page
107
Publisher
Canadian Society for Chemistry
DOI
10.1139/V11-132
Link to Publisher's Edition
http://dx.doi.org/10.1139/V11-132
ISSN (print)
00084042
Recommended Citation
Wang, Huaishan, Lap Szeto, Wesley Ting Kwok Chan, Ho-Lun Yeung, Ka-Leung Wong, and Wing-Tak Wong. "Novel Zn(II) coordination polymer based on 1,2-bis (4-pyridyl)hydrazine - From two-dimensional to three-dimensional network." Canadian Journal of Chemistry-Revue Canadienne De Chimie 90.1 (2012): 100-107.