Department of Chemistry
Narrow bandgap platinum(II)-containing polyynes with diketopyrrolopyrrole and isoindigo spacers
© 2014, Springer Science+Business Media New York.Two new solution-processible platinum(II) polyyne polymers P1 and P2 bridged by diketopyrrolopyrrole and isoindigo units have been synthesized via the CuI-catalyzed dehydrohalogenation reaction of the platinum(II) chloride precursors and the corresponding diacetylene ligands. The photophysical and electrochemical properties of P1 and P2 were investigated. These metallo-organic polymers have relatively narrow bandgaps of around 1.58–1.70 eV and broad absorption bands which are favorable for harvesting solar energy.
Acetylide, Bandgap, Diketopyrrolopyrrole, Isoindigo, Platinum
Source Publication Title
Journal of Inorganic and Organometallic Polymers and Materials
Link to Publisher's Edition
Liu, Qian, Cheuk-Lam Ho, Yih Hsing Lo, Hua Li, and Wai-Yeung Wong. "Narrow bandgap platinum(II)-containing polyynes with diketopyrrolopyrrole and isoindigo spacers." Journal of Inorganic and Organometallic Polymers and Materials 25.1 (2015): 159-168.