Department of Chemistry
Conformational engineering of co-sensitizers to retard back charge transfer for high-efficiency dye-sensitized solar cells
We demonstrate that the post-adsorption of small molecules (a phenothiazine-based dye) on the porphyrin-sensitized TiO2 anode surface plays dual roles: (1) to greatly retard the back reaction between conduction-band electrons in TiO2 and the oxidized species (I 3 -) in the electrolyte and (2) to enhance the spectral response of solar cells. These two effects finally give rise to device efficiencies exceeding 10%, which are superior to those of individual dye-sensitized devices by either porphyrin (7.4%) or phenothiazine (8.2%) under the same conditions. Experimental analyses show that the incoming small molecules are adsorbed in the interstitial site of porphyrin dyes, forming densely surface packed molecules and thus impeding the I3 - species from approaching the TiO2 surface. Since a broad range of ruthenium-based dyes and porphyrin-based photosensitizers possess relatively large molecular volumes, this method is anticipated to be applicable for further improving the energy conversion efficiency of devices sensitized by these two classes of dyes. © 2013 The Royal Society of Chemistry.
Source Publication Title
Journal of Materials Chemistry. A
Royal Society of Chemistry
Link to Publisher's Edition
Chang, S., Wang, H., Hua, Y., Li, Q., Xiao, X., Wong, W., Wong, W., Zhu, X., & Chen, T. (2013). Conformational engineering of co-sensitizers to retard back charge transfer for high-efficiency dye-sensitized solar cells. Journal of Materials Chemistry. A, 1 (38), 11553-11558. https://doi.org/10.1039/C3TA12714A